New cobalt and iron pivalate complexes with 2,2′:6′,2″-terpyridine: synthesis, structure, and magnetic properties

被引：0

作者：

K. L. Tokarev

M. A. Kiskin

A. A. Sidorov

G. G. Aleksandrov

V. N. Ikorskii

I. P. Suzdalev

V. M. Novotortsev

I. L. Eremenko

机构：

[1] M. V. Lomonosov Moscow State University,Department of Chemistry

[2] Russian Academy of Sciences,N. S. Kurnakov Institute of General and Inorganic Chemistry

[3] Siberian Branch of the Russian Academy of Sciences,International Tomography Center

[4] Russian Academy of Sciences,N. N. Semenov Institute of Chemical Physics

来源：

Russian Chemical Bulletin | 2008年 / 57卷

关键词：

iron(; ) complexes; cobalt(; ) complexes; polynuclear iron(; ) complexes; carboxylate ligands; X-ray diffraction study; Mössbauer spectroscopy; magnetic properties;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The mononuclear complexes (η3-terpy)M(Piv)2·MeCN (M = Feii (3) and Coii (4), and Piv is the pivalate anion) were synthesized by the reactions of polymeric iron(ii) and cobalt(ii) pivalates with 2,2′:6′,2″-terpyridine (terpy). The oxidation of compound 3 affords the pentanuclear heterospin iron(ii,iii) complex (η3-terpy)Fe5(μ4-O)(μ3-OH)(μ-OH)2(μ-Piv)7(η1-Piv)2 (5). All compounds were characterized by X-ray diffraction.

引用

页码：1209 / 1214

页数：5

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