Effect of poly(ethylene oxide) on the kinetics of oxidative polymerization of aniline

被引：0
|
作者：
Ya. O. Mezhuev
Yu. V. Korshak
M. I. Shtil’man
机构：
[1] Mendeleev University of Chemical Technology of Russia,
来源：
Russian Journal of General Chemistry | 2016年 / 86卷
关键词：
aniline; poly(ethylene oxide); oxidative polymerization; kinetics; reaction mechanism;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The kinetics of polymerization of aniline hydrochloride in aqueous poly(ethylene oxide) solution in the presence of ammonium persulfate have been studied. The order of the catalytic step has been found to change from first to second when the molecular weight of poly(ethylene oxide) reaches a certain value. Adsorption equilibrium is rapidly established between the monomer and its oxidation products which give rise to a new phase and exert a catalytic effect.
引用
收藏
页码：2520 / 2525
页数：5
相关论文
共 50 条
  • [31] Effect of acid on the aggregation of poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) block copolymers
    Yang, Bin
    Guo, Chen
    Chen, Shu
    Ma, Junhe
    Wang, Jing
    Liang, Xiangfeng
    Zheng, Lily
    Liu, Huizhou
    JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (46): : 23068 - 23074
  • [32] Fine polystyrene latexes with reactive poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock macrosurfactants in modified miniemulsion polymerization
    Kim, JW
    Ko, JY
    Park, JG
    Jun, JB
    Chang, HS
    Suh, KD
    JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 85 (02) : 328 - 332
  • [33] Ring-opening polymerization kinetics of ethylene oxide and propylene oxide
    Zhang Zhiguo
    Yin Hong
    PROGRESS IN CHEMISTRY, 2007, 19 (04) : 575 - 582
  • [34] IMMOBILIZATION OF POLY(ETHYLENE OXIDE) ON POLY(ETHYLENE-TEREPHTHALATE) USING A PLASMA POLYMERIZATION PROCESS
    GOMBOTZ, WR
    GUANGHUI, W
    HOFFMAN, AS
    JOURNAL OF APPLIED POLYMER SCIENCE, 1989, 37 (01) : 91 - 107
  • [35] The effect of pH on the oxidative polymerization of aniline and the morphology and properties of products
    Sapurina, I. Yu
    Stejskal, J.
    RUSSIAN CHEMICAL REVIEWS, 2010, 79 (12) : 1123 - 1143
  • [36] Reactive surfactants in heterophase polymerization. Part XXI - Kinetics of styrene dispersion polymerization stabilized with poly(ethylene oxide) macromonomers
    Lab de Chimie et Procedes de, Polymerisation/CPE, Villeurbanne, France
    Polym Adv Technol, 10 (601-607):
  • [37] Study of the Crystallization Kinetics. Poly(ethylene oxide) and a blend of poly(ethylene oxide) and poly(bisphenol A-co-epichlorohydrin)
    L. E. Cohen
    A. M. Rocco
    Journal of Thermal Analysis and Calorimetry, 2000, 59 : 625 - 632
  • [38] Crystallization Kinetics of Poly(ethylene oxide) in Confined Nanolayers
    Wang, Haopeng
    Keum, Jong K.
    Hiltner, Anne
    Baer, Eric
    MACROMOLECULES, 2010, 43 (07) : 3359 - 3364
  • [39] CRYSTALLIZATION KINETICS OF POLY(ETHYLENE OXIDE) DILUTED WITH XYLENE
    RIANDE, E
    FATOU, JG
    ALCAZAR, JC
    POLYMER, 1977, 18 (11) : 1095 - 1099
  • [40] Microviscosity in poly(ethylene oxide)-polypropylene oxide-poly(ethylene oxide) block copolymers probed by fluorescenece depolarization kinetics
    Jeon, S
    Granick, S
    Kwon, KW
    Char, K
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2002, 40 (24) : 2883 - 2888
12345