Synthesis and spectral characteristics of a novel heterometallic binuclear complex on the basis of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine

被引：0
作者：
V. V. Pakal’nis
A. Yu. Sokolov
A. A. Slisenko
M. E. Borovitov
S. P. Tunik
O. V. Sizova
机构：
[1] St. Petersburg State University,
来源：
Russian Journal of General Chemistry | 2009年 / 79卷
关键词：
Ruthenium; General Chemistry; Rhenium; Electronic Absorption Spectrum; Bipyridyl;
D O I：
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学科分类号：
摘要：
Binuclear bridged complexes [(bpy)2Ru(μ-bptz)Re(CO)3·(Hlg)](X)2 [bptz = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine; Hlg = Cl, X = BF4 or Hlg = Br, X = NO3]. Were synthesized and studied by mass spectrometry and infrared and electronic spectroscopy. The complexes give a strong long-wave band in the electronic absorption spectrum. The spectra were interpreted on the basis of TD DFT quantum-chemical calculations.
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页码：980 / 984
页数：4
相关论文
共 46 条
[1]  
Kaim W.(2002)undefined Coord. Chem. Rev. 230 127-undefined
[2]  
Scheiring T.(2001)undefined Organometallics 20 1437-undefined
[3]  
Fiedler J.(2006)undefined Inorg. Chem. 45 787-undefined
[4]  
Kaim W.(2006)undefined Inorg. Chem. 45 1613-undefined
[5]  
Nazeeruddin M.K.(1990)undefined Inorg. Chem. 29 2909-undefined
[6]  
Wang Q.(1962)undefined J. Am. Chem. Soc. 84 4432-undefined
[7]  
Cevey L.(1988)undefined Inorg. Chem. 27 1146-undefined
[8]  
Aranyos V.(1985)undefined Angew. Chem. Int. Ed. 24 684-undefined
[9]  
Liska P.(1978)undefined Inorg. Chem. 17 3334-undefined
[10]  
Figgemeier E.(1993)undefined J. Chem. Phys. 98 5648-undefined
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