Dialkyl Peroxides Decomposition in the Presence of Quaternary Ammonium Halides

被引：0
|
作者：
N.V. Maksyuta
V.Ya. Suprun
I.A. Opeida
N.A. Turovskii
机构：
[1] Litvinenko Institute of Physical Organic and Coal Chemistry,Ukrainian Academy of Sciences
[2] Martin-Luther Universität,undefined
[3] Halle-Wittenberg,undefined
来源：
Russian Journal of Organic Chemistry | 2001年 / 37卷
关键词：
Peroxide; Acetic Acid; Acetonitrile; Product Character; Halide;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Decomposition of dicumyl peroxide and cumyl tert-butyl peroxide was studied in the presence of tetraethylammonium halides in acetonitrile, dimethylformamide, 2-propanol, and acetic acid. The tetraethylammonium halides accelerate the decomposition of dialkyl peroxides in 2-propanol and acetic acid, but do not affect the reaction velocity in dimethylformamide and acetonitrile. The decomposition products character depends on the solvent nature.
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页码：814 / 818
页数：4
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