A mild and efficient method for the conversion of aldehydes into nitriles and thiols into disulfides using an ionic liquid oxidant

被引：0
作者：
Rahman Hosseinzadeh
Hamid Golchoubian
Mahboobe Nouzarian
机构：
[1] University of Mazandaran,Department of Organic Chemistry, Faculty of Chemistry
[2] University of Mazandaran,Department of Inorganic Chemistry, Faculty of Chemistry
来源：
Research on Chemical Intermediates | 2015年 / 41卷
关键词：
Hexamethylene bis(; -methylimidazolium) bis(dichloroiodate); Ionic liquid oxidant; Nitriles; Disulfides; Oxidation;
D O I：
暂无
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学科分类号：
摘要：
A simple, mild and high yielding method for the conversion of various aldehydes to nitriles has been developed using an ionic liquid reagent, hexamethylene bis(N-methylimidazolium) bis(dichloroiodate) (HMBMIBDCI), in combination with aqueous ammonia in CH3CN at room temperature. Moreover, the treatment of aromatic and aliphatic thiols with HMBMIBDCI resulted in the corresponding disulfides in solvent-free condition at room temperature.
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页码：4713 / 4725
页数：12
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共 238 条
[1]  
Vialla A(1969)Propericiazine (neuleptil), chemistry, and pharmacology Encephal 58 3-7
[2]  
Favre JD(2005)undefined Hum Psychopharmacol Clin Exp 20 511-519
[3]  
Allain H(2006)undefined Prog Neuropsychopharmacol Biol Psych 30 131-137
[4]  
Aubin HJ(2006)undefined Basic Clin Pharmacol Toxicol 99 91-95
[5]  
Frija-Orvoen E(1998)undefined Cancer Epidemol Biomark 7 65-78
[6]  
Gillet C(2007)undefined Breast Cancer Res Treat 105 7-17
[7]  
Lejoyeux M(2009)undefined Expert Opin Pharmacother 10 2445-2466
[8]  
Payen A(2008)undefined Antimicrob Agents Chemother 52 909-914
[9]  
Weber M(2004)undefined Antimicrob Agents Chemother 48 337-339
[10]  
Garcia-Acosta S(2009)undefined Drug Metab Dispos 37 536-544
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