The Chirality Parameter for Chiral Chemical Solutions

被引：0

作者：

Reza Mohammadi-Baghaee

Jalil Rashed-Mohassel

机构：

[1] University of Tehran,Center of Excellence on Applied Electromagnetic Systems, School of ECE, College of Engineering

来源：

Journal of Solution Chemistry | 2016年 / 45卷

关键词：

Dispersive chiral media; Chiral chemical solutions; Specific rotation; Circular dichroism; Condon model;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The frequency dependent chirality parameter of a chiral chemical solution is derived as a function of the specific rotation and molar ellipticity analytically by solving Maxwell’s equations for a dispersive chiral medium. The specific rotations found by measurements in a wide range of frequencies for d-glucose solution is used to find the Condon model parameters for this important chiral chemical solution. The Cotton effect is analyzed with adequate accuracy in this Condon modulation as a summation term. The frequency dependent behaviors of the real and imaginary parts of the Condon model for chiral chemical solutions are similar to the measured data for the specific rotation and circular dichroism, respectively.

引用

页码：1171 / 1181

页数：10

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