Recent approaches for asymmetric synthesis of α-amino acids via homologation of Ni(II) complexes

被引：0
|
作者：
Yibing Wang
Xiaohan Song
Jiang Wang
Hiroki Moriwaki
Vadim A. Soloshonok
Hong Liu
机构：
[1] Chinese Academy of Sciences,State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica
[2] University of Chinese Academy of Sciences,Department of Organic Chemistry I, Faculty of Chemistry
[3] Hamari Chemicals Ltd.,undefined
[4] University of the Basque Country UPV/EHU,undefined
[5] Ikerbasque,undefined
[6] Basque Foundation for Science,undefined
来源：
Amino Acids | 2017年 / 49卷
关键词：
Asymmetric synthesis; α-Amino acids; Tailor-made amino acids; Ni(II) complexes; Practicality;
D O I：
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中图分类号：
学科分类号：
摘要：
This review article critically discusses examples of asymmetric synthesis of tailor-made α-amino acids via homologation of Ni(II) complexes of glycine and alanine Schiff bases, reported in the literature from 2013 through the end of 2016. Where it is possible, reaction mechanism and origin of the stereochemical outcome is discussed in detail. Special attention is given to various aspects of practicality and scalability of the reported methods. Among the most noticeable developments in this area are novel designs of axially chiral ligands, application of electro- and mechano-chemical (ball-milling) conditions, and development of dynamic kinetic resolution procedures.
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页码：1487 / 1520
页数：33
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