Mössbauer Spectroscopy in the Characterisation of Polymetallic Cluster Compounds: a Triple Mössbauer Study of (PPh4)[Fe2Ir2(CO)12{μ3-Au(PPh3)}]

被引：0
作者：
L. Stievano
R. Della Pergola
F. E. Wagner
机构：
[1] Université,Laboratoire de Réactivité de Surface
[2] Università di Milano-Bicocca,Dip. di Scienze dell'Ambiente e del Territorio
[3] Technische Universität München,Physik
来源：
Hyperfine Interactions | 2004年 / 156-157卷
关键词：
iron; gold; iridium; polymetallic cluster compounds; Mössbauer spectroscopy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The mixed-metal cluster compound (PPh4)[Fe2Ir2(CO)12{μ3-Au(PPh3)}], which has a trigonal bipyramidal core consisting of five atoms of three different Mössbauer isotopes, was studied by 193Ir, 197Au and 57Fe Mössbauer spectroscopy. The nature and the chemical character of the atoms located at the different sites are discussed with respect to their Mössbauer spectra.
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页码：365 / 370
页数：5
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