The condition of the phase equilibrium of a soluble nanoparticle

被引：0
|
作者：
A. I. Rusanov
机构：
[1] St. Petersburg State University Mendeleev Center,
来源：
Colloid Journal | 2006年 / 68卷
关键词：
Polymer; Thin Film; Surface Tension; Phase Equilibrium; Direct Calculation;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The condition of the phase equilibrium of an amorphous nanoparticle and a nanocrystal is derived with allowance for a possible presence of movable components in a solid body and the dependence of thermodynamic surface tension on the surface curvature. With the use of dispersion forces as an example, it is demonstrated by direct calculation that a correction to the Gibbs formula for the variations of surface tension can be substantial for nanoparticles that approach molecular sizes.
引用
收藏
页码：334 / 340
页数：6
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