Synthesis, structure, and properties of phosphorus-containing bis(amidrazones)

被引：0

作者：

L. D. Popov

I. N. Shcherbakov

Yu. N. Tkachenko

S. A. Borodkin

V. A. Kogan

机构：

[1] Rostov State University,

来源：

Russian Journal of General Chemistry | 2006年 / 76卷

关键词：

General Chemistry; Phosphonium Salt; Triphenylphosphonium; Oxamide; Stable Tautomer;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Previously unknown ethenylphosphonic derivatives of bis(amidrazones) were prepared. According to spectroscopic data and quantum-chemical calculations, these compounds exist as phosphonium salts of a symmetrical linear structure with trans arrangement of the amidrazone fragments. In alkaline solutions, they are unstable and decompose to form triarylphosphine oxides. In contrast to ordinary amidrazones, their phosphorus-containing derivatives do not tend to form complexes with transition metals.

引用

页码：1219 / 1225

页数：6

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