Structural, electrical and surface morphological studies of Cd2SnO4 and Mg doped Cd2SnO4 thin films

被引:0
作者
P. Jayaram
T. P. Jaya
K. Prasanth
A. K. Abdul Gafoor
P. P. Pradyumnan
机构
[1] University of Calicut,Department of Physics
来源
Transactions of the Indian Institute of Metals | 2011年 / 64卷
关键词
cadmium stannate; spray pyrolysis; X-ray diffraction, UV-Visible; atomic force microscopy (AFM); electrical properties;
D O I
暂无
中图分类号
学科分类号
摘要
The technologically important conductive Cadmium stannate (Cd2SnO4) and Magnesium doped cadmium stannate (Cd2SnO4: Mg) thin films were prepared using Cadmium acetate and stannous chloride by spray pyrolysis technique. Films prepared are crystalline and have cubic CdO phase with SnO2. The X-ray diffraction patterns of both thin films shows perfect crystalline structure and from the data, the particle diameter of both films were calculated. Atomic Force Microscopy (AFM) of both films reveals the uniform thickness of the films and the presence of uniform grain growth in Cd2SnO4 and Mg doped Cd2SnO4 thin films. Thickness of Cadmium stannate film is 725nm and that of Magnesium doped Cadmium stannate film is 285nm. The indirect band gap energy of Cd2SnO4 film is 2.71eV and for magnesium doped Cd2SnO4 is 2.97eV were observed from the UV-Visible absorption spectrum studies. Presence of uniform grain growth is found in both thin films. The doping of Magnesium in Cadmium stannate film improves the electrical properties without affecting its structural properties.
引用
收藏
相关论文
共 38 条
[1]  
Martel A.(2000)Optical and Electrical Properties of Cd MRS Bull. 25 15-undefined
[2]  
Caballero-Briones F.(2000)SnO Physica status solidi(b) 220 261-undefined
[3]  
Oliva A.I.(2000): A Defect Semiconductor Appl. Phys. Lett. 77 2255-undefined
[4]  
Castro-Rodriguez R.(2001)Sputter Deposition and characterization of Cd J. Appl. Phys. 89 4564-undefined
[5]  
Iribarren A.(1991)SnO J. Am. Ceram. Soc. 74 662-undefined
[6]  
Bartolo-Perez P.(2001) Films J. Electrochem.Soc. 148 E341-undefined
[7]  
Pena J. L.(1972)High-Performance, Transparent Conducting Oxides Based on Cadmium Stannate Phys. Rev. B 6 453-undefined
[8]  
de Jong M. P.(1978)Recent Developments in RF-sputtered Cadmium Stannate Films Thin Solid Films 55 67-undefined
[9]  
van Ijnzendoorn L. J.(1996)undefined J of Electronic Materials 25 935-undefined
[10]  
de Voigt M. J. A.(1996)undefined Thin Solid Films 286 274-undefined