Synthesis of new heteroaromatic systems: Naphth[2,1-e] imidazo[5,1-c]-1,2,4-triazines and benz[e]imidazo-[5,1-c]-1,2,4-triazines

被引:0
作者
Bezmaternykh M.A. [1 ]
Mokrushin V.S. [1 ]
Sadchikova E.V. [1 ]
机构
[1] Ural State Technical University
关键词
Azo coupling; Benzimidazotriazine; Cyclization; Diazoimidazole; Imidazotriazine; Naphthimidazotriazine; p-toluenesulfonic acid; Phenols;
D O I
10.1007/BF02269547
中图分类号
学科分类号
摘要
Cyclization of azo compounds, synthesized 5-diazoimidazoles and 2-naphthol or p-substituted phenols, into naphth[2,1-e]imidazo[5,1-c]-1,2,4-triazines and benz[e]imidazo[5,1-c]-1,2,4-triazines occurs only in the presence of p-toluenesulfonic acid. Imidazo[4,5-d]-1,2,3-triazines are also formed in this reaction when an amide substituent is present in the imidazole ring.
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页码:465 / 471
页数:6
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