Batch sorption–photodegradation of Alizarin Red S using synthesized TiO2/activated carbon nanocomposite: an experimental study and computer modelling

被引：14

作者：

Baruah M. ^{[1
]}

Supong A. ^{[1
]}

Bhomick P.C. ^{[1
]}

Karmaker R. ^{[1
]}

Pongener C. ^{[1
]}

Sinha D. ^{[1
]}

机构：

[1] Department of Chemistry, Nagaland University, Lumami

来源：

Nanotechnology for Environmental Engineering | 2020年 / 5卷 / 01期

关键词：

Alizarin Red S; DFT; Kinetics; Photocatalysis; TiO[!sub]2[!/sub]-NP/PAC composite;

D O I：

10.1007/s41204-020-00071-3

中图分类号：

学科分类号：

摘要：

Photocatalysis is an alternative wastewater treatment method for the removal of toxic pollutants. The present work describes the hydrothermal synthesis of a new photocatalytic composite material involving activated carbon (PAC) and titanium dioxide nanoparticles (TiO2-NP) and its application for removal of Alizarin Red S (ARS) dye from wastewater. Characterization of the TiO2-NP/PAC composite was done by different analytical methods like SEM–EDX, XRD, FT-IR, photoluminescence, pHZPC and UV–visible diffuse reflectance spectroscopy. In order to evaluate the efficacy of the composite in the simultaneous adsorption and degradation of an anionic dye, ARS aqueous solution at varying TiO2-NP/PAC dosage, contact time, ARS concentrations and pH was evaluated. A composite dosage of 0.05 g shows 99.10% degradation of 20 mg l−1 ARS dye concentration in 80 min contact time at pH 2. It was observed that photocatalytic degradation of the dye followed pseudo-first-order rate kinetics and the adsorption isotherm was found to be best fitted with Freundlich isotherm model. The negative enthalpy and free energy indicated an exothermic and spontaneous process. DFT studies were used to explain the mechanism of formation of the composite, and results revealed a favourable immobilization of TiO2-NP on PAC via O-linkage of the O–Ti–O bond resulting in the formation of TiO2-NP/PAC composite. Chemical descriptors such as dipole moment, ionization energy, chemical softness and hardness and HOMO–LUMO energy obtained from DFT studies helped in understanding the comparative efficiency and reactivity of PAC and TiO2-NP/PAC towards ARS degradation. © 2020, Springer Nature Switzerland AG.

引用

共 46 条

[1]

Vijayaraghavan K., Teo T.T., Balasubramanian R., Joshi U.M., Application of Sargassum biomass to remove heavy metal ions from synthetic multi-metal solutions and urban storm water runoff, J Hazard Mater, 164, pp. 1019-1023, (2009)

[2]

Zucca P., Vinci C., Sollai F., Et al., Degradation of Alizarin Red S under mild experimental conditions by immobilized 5,10,15,20-tetrakis(4-sulfonatophenyl) porphine–Mn(III) as a biomimetic peroxidase-like catalyst, J Mol Catal A Chem, 288, pp. 97-102, (2008)

[3]

Rais Ahmad A.M., Green synthesis of Xanthan gum/Methionine-bentonite nanocomposite for sequestering toxic anionic dye, Surf Interfaces, 2, pp. 2-10, (2013)

[4]

Vandevivere P.C., Bianchi R., Verstraete W., Treatment and reuse of wastewater from the textile wet-processing industry: Review of emerging technologies, J Chem Technol Biotechnol, 72, pp. 289-302, (1998)

[5]

Petrovic M., Radjenovic J., Barcelo D., Advanced oxidation processes (AOPs) applied for wastewater and drinking water treatment. Elimination of pharmaceuticals, Holist Approach Environ, 1, pp. 63-74, (2011)

[6]

Bahrudin N.N., Nawi M.A., Immobilized titanium dioxide/powdered activated carbon system for the photocatalytic adsorptive removal of phenol, Korean J Chem Eng, 35, pp. 1532-1541, (2018)

[7]

Ouzzine M., Romero-Anaya A.J., Lillo-Rodenas M.A., Linares-Solano A., Spherical activated carbon as an enhanced support for TiO<sub>2</sub>/AC photocatalysts, Carbon N Y, 67, pp. 104-118, (2014)

[8]

Zhou W., Zhang P., Liu W., Anatase TiO<sub>2</sub> nanospindle/activated carbon (AC) composite photocatalysts with enhanced activity in removal of organic contaminant, Int J Photoenergy, 2012, pp. 28-30, (2011)

[9]

Anyika C., Asri N.A.M., Majid Z.A., Et al., Synthesis and characterization of magnetic activated carbon developed from palm kernel shells, Nanotechnol Environ Eng, 2, pp. 1-25, (2017)

[10]

Matos J., Laine J., Herrmann J.M., Effect of the type of activated carbons on the photocatalytic degradation of aqueous organic pollutants by UV-irradiated titania, J Catal, 200, pp. 10-20, (2001)

← 1 2 3 4 5 →