29Si NMR investigations on oligosilane dendrimers

被引：0

作者：

U. Herzog

C. Notheis

E. Brendler

G. Roewer

B. Thomas

机构：

[1] Institut für Analytische Chemie,

[2] Technische Universität Bergakademie Freiberg,undefined

[3] Leipziger Strasse 29,undefined

[4] D-09596 Freiberg,undefined

[5] Germany,undefined

[6] Institut für Anorganische Chemie,undefined

[7] Technische Universität Bergakademie Freiberg,undefined

[8] Leipziger Strasse 29,undefined

[9] D-09596 Freiberg,undefined

[10] Germany,undefined

来源：

Fresenius' Journal of Analytical Chemistry | 1997年 / 357卷

关键词：

Chemical Shift; Oligomer; Lower Field; Analogous Group; Silyl;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Starting with the high functionalized trisilane SiClMe(SiCl2Me)2 and tetrasilane SiMe(SiCl2Me)3 several octa- and decasilane dendrimers containing directly neighboured branchings were prepared. In these compounds the 29Si NMR chemical shifts of the different silyl groups are shifted towards lower field compared with those of analogous groups in tetra- or hexasilanes. This observation is a helpful tool for the characterization of further dendritic oligomers by 29Si NMR.

引用

页码：503 / 504

页数：1

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