Adsorption behavior of cross-linked chitosan modified by graphene oxide for Cu(II) removal

被引:0
作者
Yan Yang
Wen-qin Wu
Hai-hui Zhou
Zhong-yuan Huang
Ting-ting Ye
Rui Liu
Ya-fei Kuang
机构
[1] Hunan University,College of Chemistry and Chemical Engineering
[2] Central South University of Forestry and Technology,College of Materials Science and Engineering
来源
Journal of Central South University | 2014年 / 21卷
关键词
chitosan; graphene oxide; adsorption; Cu(II);
D O I
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中图分类号
学科分类号
摘要
Cross-linked chitosan(CS), cross-linked chitosan/graphene(CS/RGO10) and cross-linked chitosan/graphene oxide(CS/GO10) were prepared as adsorbents for Cu(II). The effects of pH, contact time, adsorbent dosage and initial concentration of Cu(II) on the adsorbing abilities of CS,CS/RGO10 and CS/GO10 to Cu(II) were investigated. The results demonstrate that the adsorption capacities of CS/GO10 and CS/RGO10 are greater than that of CS, especially at pH 5.0 and the adsorption capacities are 202.5, 150 and 137.5 mg/g, respectively. Their behaviors obey the Freundlich isotherm model very well. Additionally, CS/GO10 has the shortest time to achieve adsorption equilibrium among them and can be used as a perspective adsorbent for Cu(II).
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页码:2826 / 2831
页数:5
相关论文
共 90 条
[11]  
Haron M J(2001)Production of granular activated carbon from waste walnut shell and its adsorption characteristics for Cu Hazard Mater 85 301-315
[12]  
Janin A(2005) ion [J] Talanta 67 59-64
[13]  
Zaviska F(2008)Multi-element preconcentration of heavy metal ions from aqueous solution by APDC impregnated activated carbon [J] Hazard Mater 151 134-142
[14]  
Drogui P(2007)Adsorption of metal ions on lignin [J] Hazard Mater 147 67-73
[15]  
Blais J F(2003)Preparation of porous chitosan gel beads for copper(II) ion adsorption [J] Hazard Mater 97 219-243
[16]  
Mercier G(2002)Low-cost adsorbents for heavy metals uptake from contaminated water [J] React Funct Polym 50 181-190
[17]  
Dabrowski A(2001)Removal of copper(II) ions from aqueous solution onto chitosan and cross-linked chitosan beads [J] Ind Eng Chem Res 40 1406-1411
[18]  
Hubicki Z(2011)Cr^(VI) extraction using aliquat 336 in a hollow fiber module made of chitosan [J] Environ Sci Technol 45 10454-10462
[19]  
Podkoscielny P(2011)Few-layered graphene oxide nanosheets as superior sorbents for heavy metal ion pollution management [J] Dalton Trans 40 10945-10952
[20]  
Soylak M(2012)Removal of Pb(II) ions from aqueous solutions on few-layered graphene oxide nanosheets [J] Water, Air & Soil Pollution 224 1372-1377