Molecular beam deflection experiments on mixed clusters Permanent dipole of transition metal-C60 compounds

被引：0

作者：

I. Compagnon

R. Antoine

D. Rayane

Ph. Dugourd

M. Broyer

机构：

[1] Laboratoire de Spectrométrie Ionique et Moléculaire,

[2] Université Lyon I et CNRS,undefined

[3] 43 boulevard du 11 novembre 1918,undefined

[4] 69622 Villeurbanne Cedex,undefined

[5] France,undefined

来源：

The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics | 2001年 / 16卷

关键词：

PACS. 33.15.Kr Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility – 36.40.Cg Electronic and magnetic properties of clusters – 61.48.+c Fullerenes and fullerene-related materials;

D O I：

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学科分类号：

摘要：

Gas phase Ti-C60 clusters are studied by molecular beam electric deflection. The permanent dipole moment of the TiC60 molecule is determined. It is equal to 8.1±1.5D. This dipole is due to a transfer of electron from the transition metal atom to the C60 cage. No dipole is observed for Ti(C60)2 molecules. This is in agreement with the symmetrical dumbbell-like structure that has been previously proposed.

引用

页码：365 / 368

页数：3