Thermal and catalytic methods used for destruction of chemical warfare agents

被引:0
作者
J. Nawała
P. Jóźwik
S. Popiel
机构
[1] Military University of Technology,Faculty of Advanced Technology and Chemistry
来源
International Journal of Environmental Science and Technology | 2019年 / 16卷
关键词
Chemical warfare agents; Chemical warfare agents disposal; Enzyme catalysis; Thermocatalysis; Photocatalysis; Decontamination;
D O I
暂无
中图分类号
学科分类号
摘要
The decontamination of chemical warfare agents (CWAs) from structures, environmental media and even personnel has become an area of particular interest in recent years due to increased homeland security concerns. This article reviews applications of catalytic methods used for decontamination of CWAs. Most attention was given to the following methods: thermocatalysis, photocatalysis and enzyme catalysis among the many methods of catalytic CWA decomposition. Unfortunately, there are not enough data obtained with real CWAs due to the difficulty in handling, so we have described also data available for CWAs simulants. These methods can be useful for decontamination systems that can reduce the damage caused by possible terrorism.
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页码:3899 / 3912
页数:13
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共 464 条
[1]  
Allahyari H(2016)Diisopropyl-fluorophosphatase as a catalytic bioscavenger J Appl Biotechnol Rep 3 477-482
[2]  
Latifi AM(2003)Degradation of VX and sulfur mustard by enzymatic haloperoxidation J Appl Toxicol 23 225-233
[3]  
Amitai G(2010)The deposition of coke during carbon dioxide reforming of methane over intermetallides Catal Today 157 170-176
[4]  
Adani R(2004)Mechanism for the hydrolysis of organophosphates by the bacterial phosphotriesterase Biochemistry 43 5707-5715
[5]  
Hershkovitz M(2006)Fate of chemical warfare agents and toxic industrial chemicals in landfills Environ Sci Technol 40 4219-4225
[6]  
Bel P(2000)Thermal decomposition of chloropicrin, diphosgene and phosgene between 100 and 530 °C J Anal Appl Pyrol 53 95-105
[7]  
Rabinovitz I(2000)Thermal decomposition of bis (2-chloroethyl) sulphide and bis (2-chloroethyl) ether between 300 and 500 °C J Anal Appl Pyrol 55 203-216
[8]  
Meshulam H(2013)Enzymatic neutralization of the chemical warfare agent VX: evolution of phosphotriesterase for phosphorothiolate hydrolysis J Am Chem Soc 135 10426-10432
[9]  
Arkatova LA(2004)Chemical weapons: documented use and compounds on the horizon Toxicol Lett 149 11-18
[10]  
Aubert SD(2006)Binding of a designed substrate analogue to diisopropyl fluorophosphatase: implications for the phosphotriesterase mechanism J Am Chem Soc 128 12750-12757