Polymerization of butadiene with titanium-magnesium nanocatalysts

被引：0
|
作者：
O. V. Smetannikov
M. S. Chinova
E. A. Mushina
V. I. Kleiner
G. N. Bondarenko
B. F. Shklyaruk
机构：
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
来源：
Polymer Science Series B | 2012年 / 54卷
关键词：
Polymer Science Series; Isoprene; Butadiene; TIBA; Monomer Conversion;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The suspension polymerization of butadiene in the presence of titanium-magnesium nanocatalysts combined with triisobutylaluminum is studied. The resulting polybutadiene is shown to contain up to 99% trans-1,4-units. The dependences of polymer microstructure on temperature and the Al-to-Ti ratio are investigated. The kinetic parameters of the process and the properties of trans-1,4-polybutadiene are examined.
引用
收藏
页码：215 / 222
页数：7
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