Polymerization of butadiene with titanium-magnesium nanocatalysts

被引：0
|
作者：
O. V. Smetannikov
M. S. Chinova
E. A. Mushina
V. I. Kleiner
G. N. Bondarenko
B. F. Shklyaruk
机构：
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
来源：
Polymer Science Series B | 2012年 / 54卷
关键词：
Polymer Science Series; Isoprene; Butadiene; TIBA; Monomer Conversion;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The suspension polymerization of butadiene in the presence of titanium-magnesium nanocatalysts combined with triisobutylaluminum is studied. The resulting polybutadiene is shown to contain up to 99% trans-1,4-units. The dependences of polymer microstructure on temperature and the Al-to-Ti ratio are investigated. The kinetic parameters of the process and the properties of trans-1,4-polybutadiene are examined.
引用
收藏
页码：215 / 222
页数：7
相关论文
共 50 条
  • [1] Polymerization of butadiene with titanium-magnesium nanocatalysts
    Smetannikov, O. V.
    Chinova, M. S.
    Mushina, E. A.
    Kleiner, V. I.
    Bondarenko, G. N.
    Shklyaruk, B. F.
    POLYMER SCIENCE SERIES B, 2012, 54 (3-4) : 215 - 222
  • [2] Titanium-magnesium nanocatalysts of polymerization (Review)
    Nifant'ev, I. E.
    Smetannikov, O. V.
    Tavtorkin, A. N.
    Chinova, M. S.
    Ivchenko, P. V.
    PETROLEUM CHEMISTRY, 2016, 56 (06) : 480 - 490
  • [3] Modified titanium-magnesium nanocatalysts in the polymerization of isoprene
    Smetannikov, O. V.
    Tavtorkin, A. N.
    Nifant'ev, I. E.
    Chinova, M. S.
    Gavrilenko, I. F.
    POLYMER SCIENCE SERIES B, 2013, 55 (7-8) : 453 - 459
  • [4] Modified titanium-magnesium nanocatalysts in the polymerization of isoprene
    O. V. Smetannikov
    A. N. Tavtorkin
    I. E. Nifant’ev
    M. S. Chinova
    I. F. Gavrilenko
    Polymer Science Series B, 2013, 55 : 453 - 459
  • [5] Isoprene polymerization on titanium-magnesium catalysts
    O. V. Smetannikov
    E. A. Mushina
    M. S. Chinova
    V. M. Frolov
    Yu. Ya. Podol’skii
    G. N. Bondarenko
    B. F. Shklyaruk
    E. M. Antipov
    Polymer Science Series A, 2006, 48 : 793 - 797
  • [6] Polymerization of dienes with titanium-magnesium catalysts
    Mushina, EA
    Gavrilenko, IF
    Borodina, IA
    Tinyakova, EI
    Antipov, EM
    Bondarenko, GN
    Podolskii, YY
    Frolov, VM
    Gabutdinov, MS
    Krentsel, BA
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1996, 38 (03): : 453 - 457
  • [7] Isoprene polymerization on titanium-magnesium catalysts
    Smetannikov, O. V.
    Mushina, E. A.
    Chinova, M. S.
    Frolov, V. M.
    Podol'skii, Yu. Ya.
    Bondarenko, G. N.
    Shklyaruk, B. F.
    Antipov, E. M.
    POLYMER SCIENCE SERIES A, 2006, 48 (08) : 793 - 797
  • [8] SUPPORTED TITANIUM-MAGNESIUM CATALYST OF ETHYLENE POLYMERIZATION
    PAKHA, I
    NOVAKOVSKA, M
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1985, 27 (09): : 1840 - 1844
  • [9] POLYMERIZATION OF STYRENE ON TITANIUM-MAGNESIUM METALLOCOMPLEX CATALYSTS
    BAULIN, AA
    SIDOROVA, IP
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1982, 24 (10): : 781 - 783
  • [10] Titanium–magnesium nanocatalysts of polymerization (Review)
    I. E. Nifant’ev
    O. V. Smetannikov
    A. N. Tavtorkin
    M. S. Chinova
    P. V. Ivchenko
    Petroleum Chemistry, 2016, 56 : 480 - 490
12345