Alkyl(aryl)oxy derivatives of thulium(III)

被引：0
作者：
M. N. Bochkarev
A. A. Fagin
I. L. Fedushkin
T. V. Petrovskaya
W. J. Evans
M. A. Greci
J. W. Ziller
机构：
[1] Russian Academy of Sciences,G. A. Razuvaev Institute of Organometallic Chemistry
[2] University of California,Chemistry Department
来源：
Russian Chemical Bulletin | 1999年 / 48卷
关键词：
thulium(II); thulium(III); phenoxide; alkoxide; iodide; synthesis; structure; reduction;
D O I：
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学科分类号：
摘要：
The reactions of Tml2(DME)3 with phenol andtert-butyl alcohol afforded thulium(III)-alkoxyiodides ROTmI2(DME)2 (R=Ph and But, respectively). Their structures were determined by X-ray analysis. Monoiodides (RO)2 TmI(THF)2 were synthesized from TmI3 (THF)2 and ROH (taken in a ratio of 1∶2). Triphenoxides (RO)3Tm (R=Ph or 2,4,6-But3C6H2) were prepared by the reactions of the naphthalene thulium complex [C10H8Tm(DME)]2C10H8, with an excess of the corresponding phenol. The iodide catechoxide complex 3,6-But2C6H2O2TmI(DME)2 was prepared by the reaction of TmI2(DME)3 with 3,6-di-tert-butylbenzoquinone-1,2 or 3,6-di-tert-butylpyrocatechol.
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页码：1782 / 1785
页数：3
相关论文
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