Thermophysical properties of N-isopropyl-2-propanamine+alkanol (C1-C3) mixtures as absorbents for carbon dioxide capture

As N-isopropyl-2-propanamine+alkanol (C1-C3) systems are potential absorbents for CO2 capture, we measured density (ρ), viscosity (η) and the ultrasonic speed data (u) for N-isopropyl-2-propanamine (DIPA) with alkanol (C1-C3) at T=(298.15 and 308.15) K and 0.1 MPa. The experimental density (ρ), viscosity (η) and ultrasonic speed (u) data were used to derive excess molar volume (VmE), apparent, partial, and excess partial molar volume, deviation in viscosity and deviation in ultrasonic speed, excess isentropic compressibility (κsE\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\kappa _s^E$$\end{document}). We predicted the VmE values using the Prigogine-Flory-Patterson theory (PFP) and by Nakata and Sakurai model. An Ab initio approach was proposed for the excess isentropic compressibility (κsE)\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$(\kappa _s^E)$$\end{document} and Δη data which not only reproduces the experimental data but also gives important parameters that describe the extent of depolymerization on mixing and strength of intermolecular interactions.