Adsorption of U(VI) from aqueous solution by sulfonated ordered mesoporous carbon

被引：0
作者：
Zhi-Bin Zhang
Xiao-Feng Yu
Xiao-Hong Cao
Rong Hua
Min Li
Yun-Hai Liu
机构：
[1] East China Institute of Technology,Fundamental Science on Radioactive Geology and Exploration Technology Laboratory
[2] Ministry of Education,State Key Laboratory Breeding Base of Nuclear Resources and Environment (East China Institute of Technology)
[3] East China Institute of Technology,Chemistry, Biological and Materials Sciences Department
来源：
Journal of Radioanalytical and Nuclear Chemistry | 2014年 / 301卷
关键词：
Ordered mesoporous carbon; Sulfonation; Uranium; Adsorption; Functionalization;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The sulfonated mesoporous carbon (CMK-3-SO3H) prepared by functionalizing mesoporous carbon (CMK-3) via vapor transfer method has been explored for the removal and recovery of uranium from aqueous solutions. The influences of different experimental parameters such as solution pH, initial concentration, contact time and temperature on adsorption were investigated. The results showed that CMK-3-SO3H has the highest uranium sorption capacity at initial pH of 5.0 and contact time of 120 min, and the adsorption process could be better described by the pseudo-second-order model and Langmuir isotherm. Selective adsorption studies showed that the CMK-3-SO3H could selectively remove of U(VI), and the selectivity coefficients of mesoporous carbon in the presence of co-existing ions, Mg(II), Zn(II), Mn(II), Cu(II), Ni(II), Sr(II) and Hg(II) improved after functionalization.
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页码：821 / 830
页数：9
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