Catalytic activity of MnTUD-1 for liquid phase oxidation of ethylbenzene with tert-butyl hydroperoxide

被引：0

作者：

Gaffar Imran

Muthusamy Poomalai Pachamuthu

Rajamanickam Maheswari

Anand Ramanathan

S. J. Sardhar Basha

机构：

[1] Anna University,Department of Chemistry

[2] The University of Kansas,Center for Environmentally Beneficial Catalysis (CEBC)

[3] Anna University of Technology Madurai,Department of Chemistry

来源：

Journal of Porous Materials | 2012年 / 19卷

关键词：

Manganese; TUD-1; Mesoporous; Ethylbenzene; Oxidation; TBHP;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Manganese was incorporated into silica matrix of TUD-1 using tetraethylene glycol (TEG) as the template. Three samples with Si/Mn ratio of 115, 44 and 18 were prepared and characterized by various techniques. MnTUD-1 is shown to be mesoporous with tetrahedrally coordinated Mn when Si/Mn = 115; and nano-particles of manganese oxides are visible at higher loading of manganese (Si/Mn = 44 and 18). The catalytic activity of MnTUD-1 was explored in the liquid-phase oxidation of ethylbenzene with tert-butylhydroperoxide (TBHP) as oxidant. Influence of various reaction parameters such as time, Si/Mn ratio, oxidant and solvent were studied. Finally the catalytic activity also compared with well-known microporous and mesoporous catalysts like MnAlPO-5, Mn containing MCM-41, MCM-48 and SBA-15.

引用

页码：677 / 682

页数：5

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