Synthesis and crystal structure of the porous metal-organic coordination polymer [Zn4(Ndc)4(Oxdz)2] · 2H2O

被引：0
|
作者：
S. B. Aliev
D. G. Samsonenko
V. P. Fedin
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Novosibirsk National Research State University,undefined
来源：
Russian Journal of Coordination Chemistry | 2013年 / 39卷
关键词：
Coordination Chemistry; Coordination Polymer; Zinc Nitrate; Zinc Cation; Porous Coordination Polymer;
D O I：
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中图分类号：
学科分类号：
摘要：
New metal-organic coordination polymer [Zn4(Ndc)4(Oxdz)2] · 2H2O (H2Ndc = 2,6-naphthalenedicarboxylic acid, Oxdz = 1,3,4-oxadiazole) was prepared by heating a solution of zinc nitrate, naphthalenedicarboxylic acid, and 4-aminotriazole in DMF. Of particular interest is the in situ transformation of 4-aminotriazole into 1,3,4-oxadiazole. The structure and the composition of the obtained compounds were established by X-ray diffraction, IR spectroscopy, and elemental analysis. The metal-organic framework is electrically neutral and forms a channel structure with the pore diameter of 9 Å.
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页码：157 / 160
页数：3
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