Synthesis of Novel Well-defined End-functional Macrophotoinitiator of Poly(ε-caprolactone) by Ring-opening Polymerization

被引：0

作者：

Mustafa Degirmenci

机构：

[1] Department of Chemistry,Harran University, Faculty of Science

来源：

Polymer Journal | 2004年 / 36卷

关键词：

Ring-opening Polymerization; End-functionalization; Macrophotoinitiator; Poly(ε-caprolactone); Block Copolymer;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A new end-chain functional macrophotoinitiator of poly(ε-caprolactone) has been synthesized by controlled/living ring-opening polymerization (ROP) method. For this purpose, mono hydroxy functional a photoinitiator namely, 1-hydroxycyclohexyl phenyl ketone (HCPK), Irgacure 184, was used as the initiator for the stannous-2-ethylhexanoate (Sn(Oct)2) catalyzed living ring-opening polymerization of ε-caprolactone. The GPC and IR, H NMR, UV and fluorescence spectroscopic studies revealed that low-polydispersity poly(ε-caprolactone) with photoinitiator functionality at the end of the chain was obtained.

引用

页码：542 / 548

页数：6