Synthesis of Novel Well-defined End-functional Macrophotoinitiator of Poly(ε-caprolactone) by Ring-opening Polymerization

被引：0
|
作者：
Mustafa Degirmenci
机构：
[1] Department of Chemistry,Harran University, Faculty of Science
来源：
Polymer Journal | 2004年 / 36卷
关键词：
Ring-opening Polymerization; End-functionalization; Macrophotoinitiator; Poly(ε-caprolactone); Block Copolymer;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new end-chain functional macrophotoinitiator of poly(ε-caprolactone) has been synthesized by controlled/living ring-opening polymerization (ROP) method. For this purpose, mono hydroxy functional a photoinitiator namely, 1-hydroxycyclohexyl phenyl ketone (HCPK), Irgacure 184, was used as the initiator for the stannous-2-ethylhexanoate (Sn(Oct)2) catalyzed living ring-opening polymerization of ε-caprolactone. The GPC and IR, H NMR, UV and fluorescence spectroscopic studies revealed that low-polydispersity poly(ε-caprolactone) with photoinitiator functionality at the end of the chain was obtained.
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页码：542 / 548
页数：6
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