Stereocontrolled synthesis of trans-2-hydroxymethyl-3-methylcyclo-pentanone from (S)-(+)-citronellene

被引：0
|
作者：
A. V. Stepanov
V. V. Veselovsky
机构：
[1] N. D. Zelinsky Institute of Organic Chemistry,Russian Academy of Sciences
来源：
Russian Chemical Bulletin | 2002年 / 51卷
关键词：
(; )-(+)-citronellene; 2-hydroxymethyl-3-methylcyclopentanone; (; )-3-methyl-6-nitrohex-1-ene; silyl nitronates; intramolecular [3+2] cycloaddition; cyclopenta[; ]isoxazolidine; cyclopenta[; ]dihydroisoxazole; sesquiterpenes of the acorane series;
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摘要：
A simple route to trans-2-hydroxymethyl-3-methylcyclopentanone was proposed. The compound is a key intermediate in the synthesis of natural spirocyclic sesquiterpene of the acorane series.
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页码：359 / 361
页数：2
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