Determination of efficiency of special-purity hydrogen production from products of methane conversion with oxygen in membrane apparatus in combination with catalytic methane or carbon monoxide conversion

被引：0

作者：

Vandyshev A.B. ^{[1
]}

Kulikov V.A. ^{[1
]}

机构：

[1] Institute of Engineering Science, Ural Branch, Russian Academy of Sciences (IMASh UrO RAN), Ekaterinburg

来源：

Chemical and Petroleum Engineering | 2011年 / 47卷 / 7-8期

关键词：

Methane Conversion; Carbon Precipitation; Palladium Alloy; Conversion Catalyst; Initial Flow Rate;

D O I：

10.1007/s10556-011-9494-y

中图分类号：

学科分类号：

摘要：

Computational method has been used to show the theoretical possibility and conditions of producing special-purity hydrogen from products of methane conversion with oxygen in a high-temperature converter-membrane apparatus system in conjunction with catalytic methane or carbon monoxide conversion in high-pressure chamber. The efficiency and economic viability of the process, however, proved to be lower in this case than when products of methane reforming (conversion) with steam are used because of the need for raising the O 2/CH 4 ratio to 1.2 in order to prevent thermodynamic possibility of carbon precipitation from the gaseous phase. © 2011 Springer Science+Business Media, Inc.

引用

页码：468 / 474

页数：6

共 15 条

[1]

Krylov O.V., Commercial production of hydrogen, Katal. Prom., 2, pp. 13-29, (2007)

[2]

Patrakeev V.V., Bahteeva E.V., Mitberg E.A., Leonidov I.A., Kozhevnikov V.L., Poeppelmeier K.R., Elec-tron/hole transport in La 1-xSr xFO 3-δ , J. Solid State Chem., 172, pp. 219-231, (2003)

[3]

Kozhevnikov V.L., Leonidov I.A., Patrakeev V.V., Markov A.A., Blinovskov Y.N., Evaluation of La 1-xSr xFO 3-δ membrane reactors for partial oxidation of methane, J. Solid State Electrohem., 13, pp. 391-395, (2009)

[4]

Ioffe V.B., Fundamentals of Hydrogen Production [in Russian], (1960)

[5]

Chen Z., van Y., Elnashaie S.S.E.H., Novel circulating fast fluidizedbed membrane reformer for efficient pro-duction of hydrogen from steam reforming of methane, Chem. Eng. Sci., 58, pp. 4335-4349, (2003)

[6]

Lukyanov B.N., Andreev D.V., Catalytic membrane reformers, Khim. Prom. Segod., 3, pp. 27-32, (2009)

[7]

Vandyshev A.B., Kulikov V.A., Nikishin S.N., Increase in efficiency of preparation of specially pure hydrogen from methane in a high-temperature converter-membrane equipment system, Khim. Neftegaz. Mashinostr., 11, pp. 15-18, (2007)

[8]

Vandyshev A.B., Kulikov V.A., Principal ways of raising efficiency of special-purity hydrogen production from natural gas, Khim. Neftegaz. Mashinostr., 12, pp. 15-18, (2010)

[9]

Kirillov V.A., Meshcheryakov V.D., Modeling of membrane reactor for reforming CO with steam for producing special-purity hydrogen form synthesis gas, Khim. Prom. Segod., 3, pp. 33-36, (2009)

[10]

Vandyshev A.B., Kulikov V.A., Special-purity hydrogen production from methane in a high-temperature con-verter-membrane apparatus system combined with a carbon monoxide conversion catalyzer, Khim. Neftegaz. Mashinostr., 1, pp. 27-30, (2011)

← 1 2 →