Vibronic coupling effects in the C60 molecule

被引:0
作者
C. A. Bates
J. L. Dunn
机构
[1] University of Nottingham,School of Physics and Astronomy
来源
Applied Magnetic Resonance | 2000年 / 18卷
关键词
Fullerene; Rotational Quantum Number; Icosahedral Symmetry; Vibronic State; Quadratic Coupling;
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摘要
Many recent experiments have established that the Jahn-Teller (JT) effect plays a very important role in determining the properties of the C60 molecule. A review of the underlying theory developed by the Nottingham group is presented for cases in which distinct minima in the potential energy surface occur. This relates directly to the C60 molecule through the consideration of the T ⊗ h and H ⊗ h JT systems. When only linear coupling terms exist in the T ⊗ h system, the minima form a continuous trough of SO(3) symmetry and new methods must be used. Some details of these results are presented.
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页码:29 / 36
页数:7
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