Soot oxidation kinetics from TG experiments

被引：28

作者：

Kalogirou, Maria ^{[1
]}

Samaras, Zissis ^{[1
]}

机构：

[1] Aristotle Univ Thessaloniki, Dept Mech Engn, Lab Appl Thermodynam, Thessaloniki 54124, Greece

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2010年 / 99卷 / 03期

关键词：

Kinetics; Modelling; Oxidation; Soot; TG; DIESEL SOOT; COMBUSTION;

D O I：

10.1007/s10973-010-0707-y

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermogravimetric analysis (TG) has been used extensively for soot oxidation studies. Its known experimental and computational difficulties, however, have led to extended criticism concerning the reliability of the extracted kinetics and their potential for reliable reaction modelling. This study explores if TG kinetics could lead to successful simulation results notwithstanding the related disputes. For this, TG and mini-scale soot oxidation experiments with oxygen (O(2)) were conducted. The TG kinetics reliability was controlled through comparison with the corresponding mini-scale results and by the satisfactory simulation of the mini-scale experiments.

引用

页码：1005 / 1010

页数：6

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