Densities, Viscosities, Sound Speeds, Refractive Indices, and Excess Properties of Binary Mixtures of Isoamyl Alcohol with Some Alkoxyethanols

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作者
Mahendra Nath Roy
Radhey Shyam Sah
Prasanna Pradhan
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[1] North Bengal University,Department of Chemistry
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Excess molar volume; Refractive index; Ultrasonic speed; Viscosity deviation;
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摘要
Densities and viscosities were measured for binary mixtures of isoamyl alcohol with 2-methoxyethanol, 2-ethoxyethanol, and 2-butoxyethanol over the entire range of composition at 303.15 K, 313.15 K, and 323.15K and ultrasonic speeds and refractive indices at 303.15 K under atmospheric pressure. From the experimental values of density, viscosity, ultrasonic speed, and refractive index, the values of excess molar volume (VE), viscosity deviations (Δη), deviations in isentropic compressibility (ΔKS), and excess molar refraction (ΔR) have been calculated. The excess or deviation properties were found to be either negative or positive, depending on the molecular interactions and the nature of liquid mixtures.
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页码:316 / 326
页数:10
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