Implantation induced defects and electrical properties of Sb-implanted ZnO

被引:0
作者
Hui Xie
Tong Liu
JingMing Liu
KeWei Cao
ZhiYuan Dong
Jun Yang
YouWen Zhao
机构
[1] Chinese Academy of Sciences,Key Laboratory of Semiconductor Materials Science, Institute of Semiconductor
来源
Science China Technological Sciences | 2015年 / 58卷
关键词
ZnO; photoluminescence; Ramam scattering; Hall measurement; ion implantation; defect;
D O I
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中图分类号
学科分类号
摘要
Defects in Sb implanted ZnO single crystals have been studied by using photoluminescence (PL) spectroscopy, X-ray diffraction (XRD) and Raman scattering. Electrical properties of the samples were analyzed by Hall effect measurement. The results indicate that the annealed Sb-implanted sample is n-type with a free electron concentration of the same amplitude as the calculated implantation concentration. The well-known oxygen vacancy related deep level green PL band is suppressed in the as-implanted sample and recovers to the level close to the as-grown ZnO single crystal after annealing. These phenomena suggest that a large portion of as-implanted Sb atoms occupy oxygen lattice site in an unstable state and move to the interstitial site, forming the complex donor defect upon high temperature annealing, resulting in n-type conduction even if the implantation dose is quite high.
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页码:1333 / 1338
页数:5
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