Oxidation of organic sulfides and disulfides with a tert-butyl hydroperoxide-aluminum tri-tert-butoxide system

被引:0
作者
E. A. Zaburdaeva
V. A. Dodonov
机构
[1] N. I. Lobachevsky Nizhny Novgorod State University,
来源
Russian Chemical Bulletin | 2011年 / 60卷
关键词
oxidation; aluminum tri-; -butoxide; -butyl hydroperoxide; activated dioxygen; alkynyl sulfides; sulfones; diphenyl disulfide; -phenyl benzenethiosulfonate;
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学科分类号
摘要
Methyl phenylethynyl and phenyl phenylethynyl sulfides are selectively converted into methyl phenylethynyl and phenyl phenylethynyl sulfones, respectively, under the action of system tert-butyl hydroperoxide-aluminum tri-tert-butoxide in benzene at 20 °C. The analogous oxidation of diphenyl disulfide results in S-phenyl benzenethiosulfonate.
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页码:185 / 187
页数:2
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