Corrosion of titanium diboride in molten FLiNaK(eut)

被引：0
作者：
Viliam Pavlík
Miroslav Boča
机构：
[1] Slovak Academy of Sciences,Institute of Inorganic Chemistry
来源：
Chemical Papers | 2012年 / 66卷
关键词：
molten salts; titanium diboride; corrosion; nickel addition; tantalum addition;
D O I：
暂无
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学科分类号：
摘要：
Pure and enriched titanium dibromide (TiB2) samples (prepared by hot isostatic pressing) with different mole ratios of Ni and Ta were investigated in contact with molten eutectic salt (FLiNaK(eut); LiF/NaF/KF 42.5 mole %: 11.5 mole %: 42.0 mole %) at 600°C. Corrosion resistance of the materials was studied, the mass losses and depths of corrosion were calculated, and sample surfaces were investigated by scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX). Nickel addition decreased the corrosion resistance of TiB2. Simultaneous additions of both elements, Ni and Ta, as well as the addition of Ta only showed reducing effect on grain formation and they increased the corrosion resistance which is highest in the last case.
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页码：1073 / 1077
页数：4
相关论文
共 79 条
  • [1] Ağaoğulları D.(2011)Influences of metallic Co and mechanical alloying on the microstructural and mechanical properties of TiB Journal of the European Ceramic Society 32 1949-1956
  • [2] Gökçe H.(2011) ceramics prepared via pressureless sintering Journal of the European Ceramic Society 32 1941-1948
  • [3] Duman M. L.(1984)Microstructure evolution and tribological properties of TiB Thin Solid Films 119 241-246
  • [4] Öveçoğlu Z.(2000)/Ni-Ta cermets Materials Science and Engineering: A 282 223-231
  • [5] Bača C.(1999)TiB Electrochimica Acta 44 2859-2870
  • [6] Lenčćš E.(2008)-coated cathodes for aluminum smelting cells Applied Surface Science 254 3849-3858
  • [7] Jogl M.(1996)Controlled combustion synthesis in the Ti-B system with ZrO Materials Science and Engineering: B 39 107-110
  • [8] Neubauer A.(2008) addition Journal of the European Ceramic Society 28 3155-3164
  • [9] Vitkovič P.(1999)Pulse current plating of TiB Plasmas & Ions 2 45-56
  • [10] Merstallinger A. J.(2010) in molten fluoride Surface and Coatings Technology 204 3935-3939
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