Crystal structure of polynuclear pivalate Ni(II) complexes with butanediol

被引:0
作者
G. V. Romanenko
O. V. Kuznetsova
E. Yu. Fursova
V. I. Ovcharenko
机构
[1] Russian Academy of Sciences,Institute of the International Tomography Center, Siberian Branch
来源
Journal of Structural Chemistry | 2014年 / 55卷
关键词
nickel(II); polynuclear compounds; pivalates; butanediol; single crystal X-ray diffraction study;
D O I
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摘要
Using single crystal X-ray diffraction the structure of polynuclear [Ni6(OH)4(Piv)7(HOC4H8O)(HPiv)4], {K4[Ni12(CO3)2(Piv)16(OH)8(HOC4H8OH)2]}HPiv, {[Ni6(OH)4(Piv)6(HOC4H8O)(Me2CO)(HOC4H8OH)2]4×(Piv)4}, and {K[Ni2L2(Piv)3]}∞ complexes, where HOC4H8OH is 1,4-butanediol, HPiv is pivalic acid, and L is the anion of nitroxyl radical 2,2,5,5-tetramethyl-4-(3′,3′,3′-trifluoro-2′-oxy-1′-propenyl)-3-imidazolin-1-oxyl is determined.
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页码:481 / 487
页数:6
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