Synthesis and crystal structure of Ba2[(UO2)(C2O4)2(NCS)]NCS·7H2O

被引：0
|
作者：
Zh. V. Akhmerkina
E. V. Peresypkina
A. V. Virovets
L. B. Serezhkina
机构：
[1] Samara State University,Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of Coordination Chemistry | 2006年 / 32卷
关键词：
Hydrogen; Crystal Structure; Hydrogen Bond; Water Molecule; Oxalate;
D O I：
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中图分类号：
学科分类号：
摘要：
Single crystals of Ba2[(UO2)(C2O4)2(NCS)]NCS · 7H2O were prepared and studied by X-ray diffraction. The crystals are monoclinic, space group P21/c, Z = 4, a = 13.508(5) Å, b = 12.268(4) Å, c = 14.965(5) Å, β = 115.38(1)°, V = 2240.6(13) Å3. The main structural units in the crystal are the island complex species [(UO2)(C2O4)2(NCS)]3− corresponding to the crystal chemical group AB201 M1 (A = UO22+, B01 = C2O42−, M1 = NCS−) of uranyl complexes, which are united into a three-dimensional framework through electrostatic interactions and through hydrogen bonds involving oxalate and isocyanate ions and water molecules.
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页码：297 / 303
页数：6
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