Synthesis and crystal structure of Ba2[(UO2)(C2O4)2(NCS)]NCS·7H2O

被引：0
|
作者：
Zh. V. Akhmerkina
E. V. Peresypkina
A. V. Virovets
L. B. Serezhkina
机构：
[1] Samara State University,Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of Coordination Chemistry | 2006年 / 32卷
关键词：
Hydrogen; Crystal Structure; Hydrogen Bond; Water Molecule; Oxalate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Single crystals of Ba2[(UO2)(C2O4)2(NCS)]NCS · 7H2O were prepared and studied by X-ray diffraction. The crystals are monoclinic, space group P21/c, Z = 4, a = 13.508(5) Å, b = 12.268(4) Å, c = 14.965(5) Å, β = 115.38(1)°, V = 2240.6(13) Å3. The main structural units in the crystal are the island complex species [(UO2)(C2O4)2(NCS)]3− corresponding to the crystal chemical group AB201 M1 (A = UO22+, B01 = C2O42−, M1 = NCS−) of uranyl complexes, which are united into a three-dimensional framework through electrostatic interactions and through hydrogen bonds involving oxalate and isocyanate ions and water molecules.
引用
收藏
页码：297 / 303
页数：6
相关论文
共 50 条
  • [21] Crystal structure of (H3O)2[(UO2) 2(SeO4)3(H2O)2](H 2O)3.5
    Krivovichev S.V.
    Kahlenberg V.
    Radiochemistry, 2005, 47 (5) : 452 - 455
  • [22] Synthesis and crystal structure of [Ni(dien)2]2[Mn(NCS)6] • H2O
    Shen, L
    Xu, X
    Xu, DJ
    Xu, YZ
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2002, 18 (03) : 309 - 312
  • [23] Synthesis, Characterization, and X-ray Structure of Tetraaminoguanidinium Diuranyl Tetraoxalate Monohydrate (HAgun)4[(UO2)2(C2O4)4]•H2O
    Hussain, T. M. Ahamed
    Sivasankar, B. N.
    RADIOCHEMISTRY, 2019, 61 (04) : 434 - 442
  • [24] Crystal structure of U(VI) phthalate dihydrate [UO2(OOC) 2C6H4·H2O]·H 2O
    Charushnikova I.A.
    Krot N.N.
    Starikova Z.A.
    Radiochemistry, 2004, 46 (6) : 556 - 559
  • [25] Synthesis and structure of the first dinuclear lanthanide oxalato complexes [{MO2vO4(C2O4)2(H2O)2}2{(Ln2(H2O)4)2(C2O4)}]•7H2O (Ln = La3+, Ce3+)
    Mialane, P
    Dolbecq, A
    Costaz, G
    Lisnard, L
    Marrot, J
    Sécheresse, F
    INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (09) : 702 - 705
  • [26] Barium Oxalates Combined with Oxo-Anions and Organic Cations: Syntheses and Structures of Ba2(C2O4)(H2PO3)2 and C2H10N2•Ba(H2O)2(HC2O4)4
    Iveson, Samuel J.
    Johnston, Chloe B.
    Harrison, William T. A.
    CRYSTALS, 2011, 1 (02): : 59 - 68
  • [27] The crystal chemistry, structure and properties of a synthetic carnotite-type compound, Ba2[(UO2)2Ti2O8]
    Wallwork, Kia S.
    James, Michael
    Carter, Melody L.
    CANADIAN MINERALOGIST, 2006, 44 : 433 - 442
  • [28] Competitive coordination of the uranyl ion by perchlorate and water -: The crystal structures of UO2(ClO4)2•3 H2O and UO2(ClO4)2•5 H2O and a redetermination of UO2(ClO4)2•7 H2O
    Fischer, A
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (06): : 1012 - 1016
  • [29] Synthesis and crystal structure of Cu2{(UO2) 3[(S,Cr)O4]5}(H2O)17
    Krivovichev S.V.
    Burns P.C.
    Radiochemistry, 2004, 46 (5) : 441 - 445
  • [30] Synthesis and X-Ray Structural Investigation of K8[(UO2)2(C2O4)2(SeO4)4] • 2H2O
    Serezhkina, L. B.
    Peresypkina, E. V.
    Virovets, A. V.
    Verevkin, A. G.
    Pushkin, D. V.
    CRYSTALLOGRAPHY REPORTS, 2009, 54 (01) : 63 - 67
12345