Chemiluminescence Detection of Glucose Using Ce(IV) Oxidation in a Batch System

被引：0
作者：
Megumi Nagai
Wakayo Miyahara
Honami Sagawa
Shigeo Yamazaki
Keiitsu Saito
机构：
[1] Okayama University of Science,Separation Science Division, Faculty of Science
[2] Kobe University,Division of Natural Environment and Chemistry, Faculty of Human Development
来源：
Analytical Sciences | 2013年 / 29卷
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摘要：
A chemiluminescence method for the determination of glucose (GC) using a batch system made in our laboratory is proposed. The method is based on measures of the chemiluminesence intensity from a batch of sample GC solutions following the injection of an (NH4)2[Ce(NO3)6]-[Ru(bpy)3]Cl2 solution. The effect of the Ru complex concentration on chemiluminescence was studied. The detection limit was 0.5 × 10-8 M, and the linear calibration curve reached 10-7 M. The Ru complex was selected on the basis of its desirable performance compared to those of other photosensitizers. However, flow-injection analysis (FIA) using the Ce-Ru complex reagent was not applicable for the detection of GC.
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页码：21 / 24
页数：3
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