Structural characterization of a pentacoordinate monohydrosilane with the apical Si-H bond

被引：0
|
作者：
Saruhashi K. [1 ]
Goto K. [1 ]
Kawashima T. [1 ]
机构：
[1] Department of Chemistry, Graduate School of Science, University of Tokyo, Bunkyo-Ku, Tokyo 113-0033
来源：
Chemistry of Heterocyclic Compounds | 2001年 / 37卷 / 11期
关键词：
Apicophilicity; Hydrosilane; Intramolecular N-Si coordination;
D O I：
10.1023/A:1017903318391
中图分类号：
学科分类号：
摘要：
A pentacoordinate phenyldibenzosilazocine containing the apical Si-H bond has been prepared and characterized by 1H and 29Si NMR spectra and X-ray analysis.
引用
收藏
页码：1394 / 1395
页数：1
相关论文
共 50 条
  • [1] DANGLING BOND IN A SI-H
    BARYAM, Y
    JOANNOPOULOS, JD
    PHYSICAL REVIEW LETTERS, 1986, 56 (20) : 2203 - 2206
  • [2] DIMETHYLGERMYLENE INSERTION INTO THE SI-H BOND
    MOCHIDA, K
    HASEGAWA, A
    CHEMISTRY LETTERS, 1989, (06) : 1087 - 1088
  • [3] ORGANOSILICON NITRILES WITH SI-H BOND
    RADZHABOV, MI
    TARVERDIEV, SA
    SULTANOV, RA
    KHUDAYAROV, IA
    ZHURNAL OBSHCHEI KHIMII, 1975, 45 (02): : 422 - 424
  • [4] Si-H bond ousts a phosphorus atom
    Driess, M.
    Reisgys, M.
    Pritzkow, H.
    Angewandte Chemie (International Edition in English), 1992, 31 (11):
  • [5] STUDY OF REACTIVITY OF SI-H BOND IN POLYORGANOSILOXANES
    ANDRIANOV, KA
    KUDISHINA, VA
    MINAKOV, VT
    SHVETS, NI
    YAGUNOV, KA
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1977, 19 (05): : 325 - 329
  • [6] Steps in Si-H bond activation revealed
    Rouhi, M
    CHEMICAL & ENGINEERING NEWS, 1998, 76 (41) : 17 - 17
  • [7] INSITU STUDY OF THE SI-H BOND IN A-SI-H ULTRATHIN FILMS
    BLAYO, N
    BLOM, P
    DREVILLON, B
    PHYSICA B, 1991, 170 (1-4): : 566 - 570
  • [8] Photoinduced structural instability around the Si-H bond in undoped hydrogenated amorphous silicon
    Oheda, H
    PHYSICAL REVIEW B, 2003, 68 (08):
  • [9] ENHANCEMENT OF SI-H BOND REACTIVITY IN PENTACOORDINATED STRUCTURES
    BOYER, J
    BRELIERE, C
    CORRIU, RJP
    KPOTON, A
    POIRIER, M
    ROYO, G
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 311 (03) : C39 - C43
  • [10] Si-H Bond Activation at the Boron Center of Pentaphenylborole
    Braunschweig, Holger
    Damme, Alexander
    Hoerl, Christian
    Kupfer, Thomas
    Wahler, Johannes
    ORGANOMETALLICS, 2013, 32 (22) : 6800 - 6803
12345