Transition metal complex induced morphology change in an ABC-triblock copolymer

被引：0
|
作者：
L. Bronstein
M. Seregina
P. Valetsky
U. Breiner
V. Abetz
R. Stadler
机构：
[1] Russian Academy of Sciences,Nesmeyanov Institute of Organoelement Compounds
[2] Johannes-Gutenberg-Universität Mainz,Institut für Organische Chemie
[3] BASF AG,Makromolekulare Chemie II
[4] Universität Bayreuth,undefined
来源：
Polymer Bulletin | 1997年 / 39卷
关键词：
PMMA; Block Copolymer; Triblock Copolymer; Diblock Copolymer; Iron Carbonyl;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The short 1,2-polybutadiene center block of the ternary polystyrene-block-polybuta-diene-block-poly(methyl methacrylate) S45B6M49225 -triblock copolymer (subscripts indicating the weight fractions and the superscript indicating the total molecular weight in kg/mol) has been selectively modified by complexation with metal complexes of two different transition metals, namely Pd and Fe. These modifications cause significant variations in the microphase morphology. The original ls-morphology (spheres at lamellar interphase) belonging to the lamellar class changes via a cocontinuous morphology in the case of the Pd-complex to a morphology belonging to the cylindrical class for the Fe-complex.
引用
收藏
页码：361 / 368
页数：7
相关论文
共 50 条
  • [1] Transition metal complex induced morphology change in an ABC-triblock copolymer
    Bronstein, L
    Seregina, M
    Valetsky, P
    Breiner, U
    Abetz, V
    Stadler, R
    POLYMER BULLETIN, 1997, 39 (03) : 361 - 368
  • [2] Surface reconstruction of the lamellar morphology in ABC-triblock copolymers.
    Stocker, W
    Beckmann, J
    Stadler, R
    Rabe, JP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 410 - POLY
  • [3] A "ladder" morphology in an ABC triblock copolymer
    Kaneko, Takeshi
    Suda, Kazuya
    Satoh, Kotaro
    Kamigaito, Masami
    Kato, Toshinori
    Ono, Tomohiro
    Nakamura, Eiji
    Nishi, Toshio
    Jinnai, Hiroshi
    MACROMOLECULAR SYMPOSIA, 2006, 242 : 80 - 86
  • [4] Asymmetric ABC-triblock copolymer membranes induce a directed insertion of membrane proteins
    Stoenescu, R
    Graff, A
    Meier, W
    MACROMOLECULAR BIOSCIENCE, 2004, 4 (10) : 930 - 935
  • [5] Indication of an order-order-transition by a partial disordering in ABC-triblock copolymers
    Neumann, C
    Abetz, V
    Stadler, R
    POLYMER BULLETIN, 1996, 36 (01) : 43 - 50
  • [6] Indication of an order-order-transition by a partial disordering in ABC-triblock copolymers
    Neumann, C.
    Abetz, V.
    Stadler, R.
    Polymer Bulletin (Berlin), 1996, 36 (01):
  • [7] Morphology of ABC triblock copolymer/homopolymer blend systems
    Suzuki, J
    Furuya, M
    Inuma, M
    Takano, A
    Matsushita, Y
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2002, 40 (11) : 1135 - 1141
  • [8] Microdomain morphology of thin ABC triblock copolymer films
    Elbs, H
    Fukunaga, K
    Stadler, R
    Sauer, G
    Magerle, R
    Krausch, G
    MACROMOLECULES, 1999, 32 (04) : 1204 - 1211
  • [9] ABC Triblock Copolymer Vesicles with Mesh-Like Morphology
    Zhao, Wei
    Chen, Dian
    Hu, Yunxia
    Grason, Gregory M.
    Russell, Thomas P.
    ACS NANO, 2011, 5 (01) : 486 - 492
  • [10] Synthesis of ABC-triblock peptide-polymer conjugates for the positioning of peptide segments within block copolymer aggregates
    ten Cate, Mattijs G. J.
    Boerner, Hans G.
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2007, 208 (13) : 1437 - 1446
12345