A new scheme for analysis of pore characteristics using centrifuge driven non-toxic metal intrusion

被引:33
作者
Chen S.J. [1 ]
Tian Y. [1 ]
Li C.Y. [1 ]
Duan W.H. [1 ]
机构
[1] Department of Civil Engineering, Monash University, Clayton, 3800, VIC
基金
澳大利亚研究理事会;
关键词
BSE; Cement; Field’s metal; Image analysis; Intrusion; Pore characterization;
D O I
10.1007/s40948-016-0029-z
中图分类号
学科分类号
摘要
This study investigates the intrusion behavior of a non-toxic low-melting-point metal using centrifugation to develop a better pore characterization technique for cementitious materials such as ordinary Portland cement. This study suggests that centrifugation is a safe and effective method for driving melted low-melting-point alloys into cementitious material at pressure between 12 and 15 MPa. The non-toxic Field’s metal alloy is suggested as a replacement for the toxic Wood’s metal. For pores between 100 nm and 10 µm, Field’s metal can be used without vacuuming the sample before intrusion. For pores >10 µm, pre-vacuuming of the sample is suggested to prevent the extrusion of hardened Field’s metal from large pores. Different failure modes for the extrusion phenomenon were analyzed and the results suggest that weak bonding between the Field’s metal and the cement matrix is the main cause for the extrusion. The new scheme may also be applicable to porous geomechanical materials such as porous rock, sand and clay. © 2016, Springer International Publishing Switzerland.
引用
收藏
页码:173 / 182
页数:9
相关论文
共 22 条
[1]  
Abell A.B., Willis K.L., Lange D.A., Mercury intrusion porosimetry and image analysis of cement-based materials, J Colloid Interface Sci, 211, 1, pp. 39-44, (1999)
[2]  
Australian Standard AS 3972-2010: General Purpose and Blended Cement, (2010)
[3]  
Chen R., Whanger P., Weswig P., Selenium-induced redistribution of cadmium binding to tissue proteins: a possible mechanism of protection against cadmium toxicity, Bioinorg Chem, 4, 2, pp. 125-133, (1975)
[4]  
Diamond S., Mercury porosimetry: an inappropriate method for the measurement of pore size distributions in cement-based materials, Cem Concr Res, 30, 10, pp. 1517-1525, (2000)
[5]  
Dullien F.A.L., Wood’s metal porosimetry and its relation to mercury porosimetry, Powder Technol, 29, 1, pp. 109-116, (1981)
[6]  
Ferreira T., Rasband W., The ImageJ user guide, (2011)
[7]  
Kim D.-G., Dong X.N., Cao T., Baker K.C., Shaffer R.R., Fyhrie D.P., Yeni Y.N., Evaluation of filler materials used for uniform load distribution at boundaries during structural biomechanical testing of whole vertebrae, J Biomech Eng, 128, 1, pp. 161-165, (2006)
[8]  
Kjellsen K., Monsoy A., Isachsen K., Detwiler R., Preparation of flat-polished specimens for SEM-backscattered electron imaging and X-ray microanalysis—importance of epoxy impregnation, Cem Concr Res, 33, 4, pp. 611-616, (2003)
[9]  
Kumar R., Bhattacharjee B., Study on some factors affecting the results in the use of MIP method in concrete research, Cem Concr Res, 33, 3, pp. 417-424, (2003)
[10]  
Lange D.A., Jennings H.M., Shah S.P., Image analysis techniques for characterization of pore structure of cement-based materials, Cem Concr Res, 24, 5, pp. 841-853, (1994)