Formation of nanolaminate structures in the Ti-Si-C system: A crystallochemical study

被引：16

作者：

Konovalikhin S.V. ^{[1
]}

Kovalev D.Y. ^{[1
]}

Sytschev A.E. ^{[1
]}

Vadchenko S.G. ^{[1
]}

Shchukin A.S. ^{[1
]}

机构：

[1] Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Moscow

来源：

International Journal of Self-Propagating High-Temperature Synthesis | 2014年 / 23卷 / 04期

关键词：

combustion synthesis; crystallochemical modeling; SHS; Ti[!sub]3[!/sub]SiC[!sub]2[!/sub;

D O I：

10.3103/S1061386214040049

中图分类号：

学科分类号：

摘要：

Combustion synthesis of laminate Ti3SiC2 structures from the elements was explored by time-resolved XRD. Crystallochemical modeling and quantum-chemical calculations suggest that the laminate structure of Ti3SiC2 arises due to regular accumulation of difference between the bond lengths of Ti3SiC2 and TiC and population of thus formed vacancies with Si atoms in the TiC lattice. © 2014, Allerton Press, Inc.

引用

页码：217 / 221

页数：4

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