Unusual platinum complexes in the gas phase

被引:0
|
作者
A. A. Markov
I. A. Yakushev
A. V. Churakov
I. P. Stolyarov
N. V. Cherkashina
A. B. Kornev
M. N. Vargaftik
A. E. Gekhman
I. I. Moiseev
机构
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] Russian Academy of Sciences,Institute of Problems in Chemical Physics
来源
Doklady Physical Chemistry | 2016年 / 468卷
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摘要
Previously unknown cationic platinum complexes Pt(C5H4N)(C5H5N)+ and Pt(C5H4N)+, where platinum atom forms an unusual three-membered metallacycle with a deprotonated pyridine molecule, were detected in the gas phase by mass spectrometry and structurally characterized by DFT quantum-chemical calculations.
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页码:72 / 75
页数:3
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