Correlation of thermal properties and electrical conductivity of La0.7Sr0.3Cu0.2Fe0.8O3−δ material for solid oxide fuel cells

被引:0
作者
Jürgen Wackerl
Thomas Koppitz
Dong-Hyun Peck
Sang-Kuk Woo
Torsten Markus
机构
[1] Forschungszentrum Jülich GmbH,
[2] Korea Institute of Energy Research (KIER),undefined
来源
Journal of Applied Electrochemistry | 2009年 / 39卷
关键词
Cathode; Oxygen stoichiometry; Mixed conductor; SOFC; Perovskite;
D O I
暂无
中图分类号
学科分类号
摘要
A copper-doped ferrite with the chemical composition La0.7Sr0.3Cu0.2Fe0.8O3−δ (LaSrCuFe) was prepared using the classical ceramics method starting from the oxides. The linear thermal expansion coefficient in air was measured in the temperature range between 550 and 1,250 K to be between 10 × 10−6 and 15 × 10−6 K−1. The electrical conductivity in air was found to be higher than 100 S cm−1 for temperatures lower than 1,100 K. A change of oxygen stoichiometry was found above 650 K in an atmosphere of 20 vol% oxygen with argon. This change can be correlated with the electrical conductivity.
引用
收藏
页码:1243 / 1249
页数:6
相关论文
共 85 条
  • [11] Xiong Y(2006)undefined J Power Source 162 30-undefined
  • [12] Kato T(2004)undefined Appl Catal Gen 262 167-undefined
  • [13] Yokokawa H(2004)undefined Solid State Ionics 175 73-undefined
  • [14] Kawada T(2001)undefined Meas Sci Technol 12 R1-undefined
  • [15] Fleig J(1995)undefined J Struct Chem 119 260-undefined
  • [16] Ormerod RM(2006)undefined Solid State Ionics 177 3205-undefined
  • [17] Tietz F(2004)undefined Solid State Ionics 175 79-undefined
  • [18] Petric A(2006)undefined J Mater Chem 16 3624-undefined
  • [19] Huang P(2006)undefined Solid State Ionics 177 3285-undefined
  • [20] Tietz F(2005)undefined J Solid State Chem 178 921-undefined