Palladium acetate complexes with morpholine and 4-methylmorpholine. The structure of Pd(C4H9ON)2(OAc)2 · 2H2O

被引：0
作者：
O. N. Shishilov
T. A. Stromnova
A. V. Churakov
L. G. Kuz’mina
I. A. Efimenko
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
来源：
Russian Journal of Inorganic Chemistry | 2006年 / 51卷
关键词：
Acetate; 2H2O; Inorganic Chemistry; Palladium; Spectroscopic Data;
D O I：
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中图分类号：
学科分类号：
摘要：
Methods for the synthesis of new palladium(II) acetate complexes [L2Pd(OCOCH3)2], where L is N-coordinated morpholine (C4H9ON) or 4-methylmorpholine (C5H11ON), have been developed. The structure of the complex (C4H9ON)2Pd(OAc)2 · 2H2O (1) has been established by X-ray diffraction. The crystals of 1 are monoclinic (C12H26O8N2Pd, M = 434.76), space group P2(1)/c, a = 9.129(3) Å, b = 16.227(5) Å, c = 6.159(2) Å, V = 878.5(5) Å3, Z = 2. The palladium atom has a square-planar environment with the trans arrangement of ligands. The complex (C5H11ON)2Pd(OAc)2 (2) has a similar structure, according to spectroscopic data.
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页码：574 / 580
页数：6
相关论文
共 47 条
[1]  
Rozenberg V.(1969)undefined Nature 222 385-undefined
[2]  
Van Camp L.(2005)undefined Birzha Intellektual’noi Sobstvennosti 4 26-undefined
[3]  
Trosko J. E.(2003)undefined Inorg. Chim. Acta 350 283-undefined
[4]  
Mancouz V. H.(1990)undefined Acta. Crystallogr., Sect. A: Found. Crystallogr. 46 467-undefined
[5]  
Efimenko I. A.(1974)undefined Can. J. Chem. 52 1241-undefined
[6]  
Ermakov V. A.(1985)undefined Inorg. Chem. 24 811-undefined
[7]  
Stromnova T. A.(1998)undefined J. Am. Chem. Soc. 120 6531-undefined
[8]  
Paschenko D. V.(1998)undefined J. Org. Chem. 63 5071-undefined
[9]  
Boganova L. I.(2002)undefined J. Organomet. Chem. 658 159-undefined
[10]  
Sheldrick G. M.(1990)undefined Acta Crystallogr. Sect. C: Struct. Commun. 46 56-undefined
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