A new Cd(II)-containing ionic liquid: Synthesis, characterization and electrocatalysis

被引：0
|
作者：
Ruirui Zhuang
Fangfang Jian
Kefei Wang
机构：
[1] Qingdao University of Science and Technology,New Materials and Function Coordination Chemistry Laboratory
来源：
Journal of Chemical Sciences | 2010年 / 122卷
关键词：
Metal-containing ionic liquid; cadmium chloride; crystal structure; electrocatalysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The present work reports on the synthesis, characterization and performance of a new metal-containing ionic liquid [(C4H9)2-bta][(C4H9-bta)CdCl3] (bta = benzotriazole) as electrocatalyst for hydrogen peroxide reduction. The structure of the Cd(II)-containing ionic liquid (Cd-IL) has been characterized by X-ray crystallography, IR spectroscopy and elemental analysis. The molecule contains one 1,3-dibutyl-benzotriazolium cation and an anionic Cd coordination entry. The electrochemical property of Cd-IL bulk-modified carbon paste electrode (Cd-IL/CPE) has been studied by cyclic voltammetry. The Cd-IL has functions both as a binder and an electrocatalyst. The Cd-IL/CPE shows good electrocatalytic activity towards the reduction of hydrogen peroxide.
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收藏
页码：631 / 637
页数：6
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