A Highly Selective and Sensitive Probe for Cu2+ Based on Rhodamine-Pyridazine Conjugate and its Application

被引:0
作者
Peigang Ding
Shao Li
Linchao Yang
Junye Cheng
Zhenji Wang
Yufen Zhao
Yong Ye
机构
[1] Zhengzhou University,Phosphorus Chemical Engineering Research Center of Henan Province, The College of Chemistry and Molecular Engineering
[2] Zhengzhou University,School of Pharmaceutical Science
[3] Tsinghua University,Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry
来源
Journal of Fluorescence | 2015年 / 25卷
关键词
Rhodamine B; Fluorescence; Chemodosimeter; Cu;
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学科分类号
摘要
A naked-eye fluorescent chemodosimeter based on rhodamine-pyridazine conjugate L was synthesized and characterized. L exhibited high selectivity and excellent sensitivity in both absorbance and fluorescence detection of Cu2+ in aqueous solution with a broad pH span (1–10). The detection limit of the probe was shown to be up to 0.336 ppm. A simple paper test-strip system for the rapid monitoring of Cu2+ was developed, indicating its convenient use in environmental samples. Furthermore, fluorescence imaging experiments of Cu2+ in living MGC803 cells demonstrated its value of practical applications in biological systems.
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页码:15 / 24
页数:9
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