Sunlight-Assisted Photocatalytic Oxidation of Methane over Uranyl-Anchored MCM-41

被引：0
作者：
Vidya Krishna
Valmik S. Kamble
Parasuraman Selvam
Narendra M. Gupta
机构：
[1] Indian Institute of Technology-Bombay,Department of Chemistry
[2] Bhabha Atomic Research Centre,Applied Chemistry Division
来源：
Catalysis Letters | 2004年 / 98卷
关键词：
Uranyl ion; MCM-41; Photocatalysis; Sunlight; Methane decomposition; VOCs;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Uranyl ions anchored within the mesopores of MCM-41 silicate host matrix served as highly efficient heterogeneous catalysts for sunlight-assisted room-temperature photooxidation of methane in the presence of air to selectively form carbon dioxide. The extent of conversion depended upon the methane content; lower the concentration, faster was the completion of reaction. It was also confirmed that no thermocatalytic reaction occurred below 200 °C in the absence of radiation, other test conditions remaining the same. These results are of relevance from the point of view of abatement of VOCs in the environment.
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页码：113 / 116
页数：3
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