Synthesis and physical properties of pH-sensitive semi-IPN hydrogels based on poly(dimethylaminoethyl methacrylate-co-PEG dimethacrylate) and poly(acrylic acid)

被引:0
作者
Goo Myun Kim
Won Ho Jo
机构
[1] Seoul National University,Hyperstructured Organic Materials Research Center and School of Materials Science and Engineering
来源
Fibers and Polymers | 2006年 / 7卷
关键词
Acrylic acid; Complex; Dimethylaminoethyl methacrylate; Hydrogel; Semi-IPNs;
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学科分类号
摘要
Hydrogels of semi-interpenetrating polymer networks (semi-IPNs) were prepared by two step reactions. Dimethylaminoethyl methacrylate (DMAM) and poly(ethylene glycol)-dimethacrylate (PEGDM) were copolymerized to yield hydrogels, and then acrylic acid (AA) monomer were adsorbed in the hydrogels followed by polymerization of AA to produce semi-IPNs. The swelling behavior of semi-IPNs depends largely on pH of medium, showing that the degree of swelling of the semi-IPNs exhibits a minimum at pH 6.0. It is observed that the elastic modulus of semi-IPNs is closely related to its swelling behavior.
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页码:223 / 228
页数:5
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