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Transformation of 1-(acyl)(2-haloethyl)amino-9,10-anthraquinones into 1-(2-acyloxyethylamino)-9,10-anthraquinones
被引：0
作者：
L. M. Gornostaev
M. S. Sokolova
机构：
[1] Astaf’ev Krasnoyarsk State Pedagogical University,
来源：
Russian Journal of Organic Chemistry
|
2006年
/
42卷
关键词：
Anthraquinone;
Ethyl Benzoate;
Benzenesulfonyl Chloride;
Nitrobenzamide;
Probable Reaction Path;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Acylation of 1-(2-haloethylamino)-9,10-anthraquinones gave 1-[(2-haloethyl)(aroyl, hetaroyl, or acetyl)amino]-9,10-anthraquinones which were converted into the corresponding 1-[2-(aroyloxy, hetaroyloxy, or acetoxy)ethylamino]-9,10-anthraquinone on keeping in dimethylformamide. According to the experimental data (including those obtained by kinetic study), the transformation involves intramolecular migration of the acyl group through aziridinium or oxazolidinium intermediates.
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页码：1473 / 1476
页数：3
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