Organometallic synthesis in the furazan series. 4. Reactions of azofurazans with organolithium compounds

被引:0
作者
A. B. Sheremetev
E. A. Ivanova
E. V. Shatunova
D. E. Dmitriev
N. E. Kuz"mina
机构
[1] Russian Academy of Sciences,N. D. Zelinsky Institute of Organic Chemistry
[2] Russian Academy of Sciences,N. S. Kurnakov Institute of General and Inorganic Chemistry
来源
Russian Chemical Bulletin | 2004年 / 53卷
关键词
azofurazans; organolithium compounds; electrophilic addition; redox reaction; X-ray diffraction study;
D O I
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学科分类号
摘要
The reactions of azofurazans, including macrocyclic azofurazans, with BunLi and Li derivatives of methylfurazans were studied. Several competitive processes were found to occur: the addition of a Li reagent at the N=N bond, the redox reaction giving rise to hydrazofurazans, and the reaction of the side chain of azofurazan.
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页码:615 / 621
页数:6
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